Yes, That was helpful thanks.
I still don't understand why I get "The ETag header's syntax isn't valid." for this header Last-Modified: Fri, 23 Aug 2013 10:18:55 GMT.
I fixed my other headers issues with this
<FilesMatch "^autoptimize_.*\.php$">
Header unset Cache-Control
Header merge Cache-Control "proxy-revalidate"
</FilesMatch>